Myers, DJ and Shigeiwa, Motoyuki and Cherayil, Binny J and Fayer, MD (2001) Temperature and density dependent solute vibrational relaxation in supercritical fluoroform. In: Journal of Chemical Physics, 115 (10). p. 4689.
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Temperature- and density-dependent vibrational relaxation data for the v6 asymmetric stretch of W(CO)6 in supercritical fluoroform (trifluoromethane, CHF3) are presented and compared to a recent theory of solute vibrational relaxation. The theory, which uses thermodynamic and hydrodynamic conditions of the solvent as input parameters, shows very good agreement in reproducing the temperature- and density-dependent trends of the experimental data with a minimum of adjustable parameters. Once a small number of parameters are fixed by fitting the functional form of the density dependence, there are no adjustable parameters in the calculations of the temperature dependence. © 2001 American Institute of Physics.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to American Institute of Physics.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||02 Aug 2011 06:20|
|Last Modified:||02 Aug 2011 06:20|
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