Bharathi, Saravana D and Samuelson, Ashoka G and Prasad, Shashidhar J and Sridhar, MA (2001) The first copper(I) complex of tris(hydroxymethyl)phosphine. In: Inorganic Chemistry Communications, 4 (9). pp. 490-492.
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The first copper(I) complex of tris(hydroxymethyl)phosphine (THP) has been synthesized from a reaction with [Cu(CH3CN)4]ClO4. The crystal structure and spectroscopic properties of this complex showing the tetrahedral coordination around copper and a deprotonated THP coordinated to Cu through P are presented.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Keywords:||Tris(hydroxymethyl)phosphine;Copper(I) complex;Water soluble; X-ray structure.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||02 Aug 2011 06:15|
|Last Modified:||02 Aug 2011 06:15|
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