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A stereospecific approach to cis-anti-cis triquinanes

Srikrishna, A and Reddy, Jagadeeshwar T and Palani, N and Balasubramanian, KK (2003) A stereospecific approach to cis-anti-cis triquinanes. In: Synthetic Communications, 33 (9). pp. 1537-1544.

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Official URL: http://www.tandfonline.com/doi/full/10.1081/SCC-12...

Abstract

A methodology for the synthesis of compounds containing the cis-anti-cis fused triquinane system has been developed starting from tricyclo[5.2. 1.0(2.6)]deca-4,8-dien-3-(exo)ol 6 involving Ireland ester Claisen rearrangement and intramolecular diazo ketone cyclopropanation reactions as key steps.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Keywords: Triquinanes;Ireland-Claisen rearrangement;Intramolecular cyclopropanation;Regiospecific cyclopropane reductive cleavage.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Aug 2011 09:08
Last Modified: 04 Aug 2011 09:08
URI: http://eprints.iisc.ernet.in/id/eprint/39762

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