ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Enantiospecific synthesis of functionalised bicyclo[3.3.1] nonanes from 10-bromocarvones via tandem intermolecular alkylation-intramolecular Michael addition sequence

Srikrishna, A and Kumar, PP and Reddy, TJ (2003) Enantiospecific synthesis of functionalised bicyclo[3.3.1] nonanes from 10-bromocarvones via tandem intermolecular alkylation-intramolecular Michael addition sequence. In: ARKIVOC (part 3). pp. 55-66.

[img] PDF
Synthesis,_chiroptical.pdf - Published Version
Restricted to Registered users only

Download (117Kb) | Request a copy
Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2003...

Abstract

A simple and convenient tandem methodology for the enantiospecific generation of functionalised bicyclo[3.3.1] nonanes 9,14-18, via intermolecular alkylation of Michael donors with 10-bromocarvones 7, 10 and 11, followed by intramolcular Michael addition, is achieved. An unsuccessful attempt for the extension of the methodology for a possible short enantiospecific approach to AB-ring system 22 of taxanes via the allyl bromide 21, is also described.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Arkat USA Inc.
Department/Centre: Others
Date Deposited: 29 Aug 2011 08:00
Last Modified: 29 Aug 2011 08:00
URI: http://eprints.iisc.ernet.in/id/eprint/40086

Actions (login required)

View Item View Item