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Enantiospecific first total synthesis of cucumin-H

Srikrishna, A and Dethe, Dattatraya H (2011) Enantiospecific first total synthesis of cucumin-H. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 50 (8). pp. 1092-1106.

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Official URL: http://nopr.niscair.res.in/handle/123456789/12513

Abstract

Enantiospecific first total synthesis of the linear triquinane sesquiterpene cucumin-H has been described. (R)-Limonene has been employed as the chiral starting material and a combination of Claisen rearrangement, intramolecular cyclopropanation and Nazarov reactions are employed for the regio- and stereospecific construction of the triquinane framework.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to National Institute of Science Communication and Information Resources.
Keywords: Cucumanes;triquinanes;limonene;Nazarov cyclisation;Claisen rearrangement;intramolecular cyclopropanation
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 15 Sep 2011 11:01
Last Modified: 15 Sep 2011 11:01
URI: http://eprints.iisc.ernet.in/id/eprint/40454

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