Mehta, Goverdhan and Bera, Mrinal K (2004) Towards an enantiospecific total synthesis of garsubellin A and related phloroglucin natural products: the alpha-pinene approach. In: Tetrahedron Letters, 45 (6). pp. 1113-1116.
The first enantiospecific approach to garsubellin A and related phloroglucin natural product nemorosone, of contemporary interest from (−)alpha -pinene, has been delineated. Through a series of stereospecific operations, the requisite stereochemistry of the prenyl groups has been secured. Kende cyclization has been employed as the key step to construct the functionalized bicyclo[3.3.1]nonane core.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Elsevier Science Ltd.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||22 Jun 2004|
|Last Modified:||19 Sep 2010 04:12|
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