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Total synthesis of panaxytriol and panaxydiol

Prasad, Kavirayani R and Swain, Bandita (2011) Total synthesis of panaxytriol and panaxydiol. In: Tetrahedron: Asymmetry, 22 (12). pp. 1261-1265.

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Official URL: http://dx.doi.org/10.1016/j.tetasy.2011.07.007

Abstract

The enantioselective total synthesis of the diyne containing natural products panaxytriol and (3S,10R)-panaxydiol from L-tartaric acid is reported. Key steps in the synthesis include the elaboration of a gamma-hydroxy amide derived from tartaric acid to the required alkyne and the formation of the desired diyne unit by a Cadiot-Chodkiewicz coupling. (C) 2011 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Nov 2011 09:31
Last Modified: 04 Nov 2011 09:31
URI: http://eprints.iisc.ernet.in/id/eprint/41836

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