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Mass spectrometric and electrochemical studies of thermodynamic properties of liquid and solid phases in the CaO Al2O3 system

Allibert, M and Lourtau, R and Jacob, KT and Chatillon, C (1981) Mass spectrometric and electrochemical studies of thermodynamic properties of liquid and solid phases in the CaO Al2O3 system. In: Journal of the American Ceramic Society, 64 (5). pp. 307-314.

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Official URL: http://onlinelibrary.wiley.com/doi/10.1111/j.1151-...

Abstract

The activities of CaO and Al2O3 in lime-alumina melts were studied by Knudsen cell-mass spectrometry at 2060 K. Emf of solid state cells, with CaF2 as the electrolyte, was measured from 923 to 1223 K to obtain the free energies of formation of the interoxide compounds. The results are critically evaluated in the light of data reported in the literature on phase equilibria, activities in melts, and stabilities of compounds. A coherent set of data is presented, including the previously unknown free energy of formation of CaO.6Al2O3 and the temperature dependence of activities in the liquid phase.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to John Wiley and Sons.
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 01 Dec 2011 07:15
Last Modified: 01 Dec 2011 07:15
URI: http://eprints.iisc.ernet.in/id/eprint/42516

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