ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

An Enantiospecific Approach to Tetraquinane Diterpenes Crinipellins: Synthesis of Norcrinipellins

Srikrishna, A and Gowri, V (2011) An Enantiospecific Approach to Tetraquinane Diterpenes Crinipellins: Synthesis of Norcrinipellins. In: Synlett (18). pp. 2652-2656.

[img] PDF
Syn_18_2011.pdf - Published Version
Restricted to Registered users only

Download (156Kb) | Request a copy
Official URL: https://www.thieme-connect.de/DOI/DOI?10.1055/s-00...

Abstract

An enantiospecific approach to the synthesis of tetraquinane diterpene crinipellins is described. The cyclopentane ring in campholenaldehyde was identified as the B ring. Two rhodium carbenoid CH insertion reactions for the construction of A and C rings and an intramolecular Michael addition reaction for the D ring of crinipellins were employed as key strategies for the enantiospecific synthesis of norcrinipellins.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Thieme Medical Publishers.
Keywords: crinipellins;tetraquinanes;enantiospecific synthesis; campholenaldehyde;intramolecular Michael addition
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 07 Dec 2011 06:40
Last Modified: 07 Dec 2011 06:40
URI: http://eprints.iisc.ernet.in/id/eprint/42530

Actions (login required)

View Item View Item