Srikrishna, A and Gowri, V (2011) An Enantiospecific Approach to Tetraquinane Diterpenes Crinipellins: Synthesis of Norcrinipellins. In: Synlett (18). pp. 2652-2656.
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An enantiospecific approach to the synthesis of tetraquinane diterpene crinipellins is described. The cyclopentane ring in campholenaldehyde was identified as the B ring. Two rhodium carbenoid CH insertion reactions for the construction of A and C rings and an intramolecular Michael addition reaction for the D ring of crinipellins were employed as key strategies for the enantiospecific synthesis of norcrinipellins.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Thieme Medical Publishers.|
|Keywords:||crinipellins;tetraquinanes;enantiospecific synthesis; campholenaldehyde;intramolecular Michael addition|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||07 Dec 2011 06:40|
|Last Modified:||07 Dec 2011 06:40|
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