Shekar, SC and Easwaran, KRK (1982) Proline Ring Conformations Corresponding to a Bistable Jump Model from $^{13}C$ spin-Lattice Relaxation Times. In: Biopolymers, 21 (8). pp. 1479-1487.
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Abstract
A formalism for extracting the conformations of a proline ring based on the bistable jump model of R. E. London [(1978) J. Am. Chem. Soc. 100, 2678-2685] from $^{13}C$ spin-lattice relaxation times ($T_1$) is given. The method is such that the relaxation data are only partially used to generate the conformations; these conformations are constrained to satisfy the rest of the relaxation data and to yield acceptable ring geometry. An alternate equation for $T_1$ of $^{13}C$ nuclei to that of London is given. The formalism is illustrated through an example.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | The copyright belongs to John Wiley & Sons, Inc. |
| Department/Centre: | Division of Biological Sciences > Molecular Biophysics Unit |
| Date Deposited: | 08 Dec 2005 |
| Last Modified: | 19 Sep 2010 04:21 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/4272 |
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