Srikrishna, Adusumilli and Gowni, Vijayendran (2011) Enantiospecific synthesis of angular triquinanes. In: Tetrahedron: Asymmetry, 22 (14-15). pp. 1553-1559.
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Official URL: http://dx.doi.org/10.1016/j.tetasy.2011.08.016
Abstract
The enantiospecific synthesis of angular triquinanes has been developed starting from the readily available (S)-campholenaldehyde. Two alternate strategies have been used, one employing a Johnson's orthoester Claisen rearrangement followed by an intramolecular cyclopropanation and regioselective cyclopropane ring cleavage, and a second one based on a RCM reaction. (C) 2011 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article belongs to Elsevier Science. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 23 Dec 2011 11:47 |
| Last Modified: | 23 Dec 2011 11:47 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/42852 |
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