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Cubane ${Cu^{II}_4}$ Cluster as a Precursor for the Preparation of a Mixed-Valent ${Cu^{II}_{12}Cu^{I}_2}$ Core

Mukherjee, Arindam and Nethaji, Munirathinam and Chakravarty, Akhil R (2004) Cubane ${Cu^{II}_4}$ Cluster as a Precursor for the Preparation of a Mixed-Valent ${Cu^{II}_{12}Cu^{I}_2}$ Core. In: Angewandte Chemie International Edition, 43 (1). pp. 87-90.

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Abstract

Current interests in the chemistry of high-nuclearity transition- metal complexes draw from their utility in the emerging science of nanomaterials,[1] as models for the multimetal active sites of metal-storage proteins,[2] and as single molecule magnets (SMMs).[3,4] In addition, such super-sized molecules often show a variety of supramolecular interactions.[5] The "self-assembly" process of generating a high-nuclearity cluster from a mono- or dimeric precursor generally involves low-dentate organic ligands.

Item Type: Journal Article
Additional Information: The copyright belongs to WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 08 Dec 2005
Last Modified: 19 Sep 2010 04:21
URI: http://eprints.iisc.ernet.in/id/eprint/4306

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