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Electrostatic vs. Orbital Control of Facial Selectivities in \pi Systems: Experimental and Theoretical Study of Electrophilic Additions to 7-Isopropylidenenorbornanes

Mehta, Goverdhan and Khan, Faiz Ahmed and Gadre, Shridhar R and Shirsat, Rajendra N and Ganguly, Bishwajit and Chandrasekhar, Jayaraman (1994) Electrostatic vs. Orbital Control of Facial Selectivities in \pi Systems: Experimental and Theoretical Study of Electrophilic Additions to 7-Isopropylidenenorbornanes. In: Angewandte Chemie International Edition in English, 33 (13). pp. 1390-1392.

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Abstract

Evaluation of the relative importance of electrostatic and orbital effects in determining facial selectivities of \pi systems (\pi -facial selectivity) in nucleophilic and electrophilic additions to trigonal carbon centers is currently a topic of intense debate.

Item Type: Journal Article
Additional Information: The copyright belongs to VCH Verlagsgesellschaft mbH, Germany.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 14 Dec 2005
Last Modified: 19 Sep 2010 04:21
URI: http://eprints.iisc.ernet.in/id/eprint/4373

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