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Synthesis and Molecular Structures of Carboxylic Acid Group Bearing Two Ketoimines that Exist in Enaminone Form

Murugavel, Ramaswamy and Singh, Mayank Pratap and Nethaji, M (2012) Synthesis and Molecular Structures of Carboxylic Acid Group Bearing Two Ketoimines that Exist in Enaminone Form. In: Journal of Chemical Crystallography, 42 (1). pp. 12-17.

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Abstract

Condensation reaction involving substituted aminobenzoic acids (2-aminobenzoic acid and 4-aminobenzoic acid) and acetylacetone results in the formation of ketoimines [CH3C(= O)CH2C(CH3)(= NAr)] (Ar = C6H4COOH-4; 1 and C6H4COOH-2 2). Compounds 1 and 2 have been characterized by spectroscopic techniques and by single crystal X-ray diffraction studies. The absorption, emission and lifetime measurement studies have also been performed for the new compounds. While compound 1 forms a linear chain type of aggregation though intermolecular hydrogen bonding, compound 2 forms a discrete dimer in the solid state.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Springer.
Keywords: Ketoimines;Enaminone tautomer;X-ray structures;Synthesis; Ligands
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 20 Apr 2012 12:39
Last Modified: 20 Apr 2012 12:39
URI: http://eprints.iisc.ernet.in/id/eprint/44358

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