ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature

Lamani, Manjunath and Devadig, Pradeep and Prabhu, Kandikere Ramaiah (2012) A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature. In: Organic and Biomolecular Chemistry, 10 (14). pp. 2753-2759.

[img] PDF
A_non-metal.pdf - Published Version
Restricted to Registered users only

Download (190Kb) | Request a copy
Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2012...

Abstract

A novel non-metal catalyzed oxidation of organic azides to nitriles under solvent-free conditions is presented employing catalytic amounts of KI, and DABCO in aq. TBHP at room temperature. This nonmetal catalyzed oxidation of azides provides good selectivity as double and triple bonds were not oxidized under the present reaction conditions.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 20 Apr 2012 12:37
Last Modified: 20 Apr 2012 12:37
URI: http://eprints.iisc.ernet.in/id/eprint/44363

Actions (login required)

View Item View Item