Srikrishna, A and Gowri, V (2012) Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one. In: Tetrahedron, 68 (14). pp. 3046-3055.
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Official URL: http://dx.doi.org/10.1016/j.tet.2012.02.018
Abstract
Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin. (C) 2012 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright of this article is belongs to Elsevier Science. |
| Keywords: | Crinipellins;Tetraquinanes;Intramolecular rhodium carbenoid CH insertion;Enantiospecific synthesis;Campholenaldehyde; Intramolecular Michael addition |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 23 Aug 2012 07:37 |
| Last Modified: | 23 Aug 2012 07:39 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/44469 |
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