Srikrishna, A and Gowri, V (2012) Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one. In: Tetrahedron, 68 (14). pp. 3046-3055.
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Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin. (C) 2012 Elsevier Ltd. All rights reserved.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article is belongs to Elsevier Science.|
|Keywords:||Crinipellins;Tetraquinanes;Intramolecular rhodium carbenoid CH insertion;Enantiospecific synthesis;Campholenaldehyde; Intramolecular Michael addition|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||23 Aug 2012 07:37|
|Last Modified:||23 Aug 2012 07:39|
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