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Evidence for the ``Amphoteric'' Nature of Fluorine in Halogen Bonds: An Instance of Cl center dot center dot center dot F Contact

Dikundwar, Amol G and Row, Tayur Guru N (2012) Evidence for the ``Amphoteric'' Nature of Fluorine in Halogen Bonds: An Instance of Cl center dot center dot center dot F Contact. In: Crystal Growth & Design, 12 (4). pp. 1713-1716.

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Official URL: http://pubs.acs.org/doi/abs/10.1021/cg3002477

Abstract

This study presents unambiguous experimental evidence in support of the highly debated ``halogen bond donor'' character of organic fluorine. Two examples of intermolecular Cl center dot center dot center dot F contacts, with F-atom as halogen bond acceptor and donor, have been analyzed by in situ cryocrystallography and theoretical charge density studies.

Item Type: Journal Article
Additional Information: Copyright of this article is belongs to American Chemical Society.
Keywords: CHARGE-DENSITY ANALYSIS;X-RAY;INTERMOLECULAR INTERACTIONS; CRYSTAL-STRUCTURE;ORGANIC FLUORINE;PACKING;GEOMETRY;FORCES
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 14 Aug 2012 05:35
Last Modified: 14 Aug 2012 05:36
URI: http://eprints.iisc.ernet.in/id/eprint/44495

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