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A novel oxidative transformation of alcohols to nitriles: an efficient utility of azides as a nitrogen source

Rokade, Balaji V and Malekar, Sanjeev K and Prabhu, Kandikere Ramaiah (2012) A novel oxidative transformation of alcohols to nitriles: an efficient utility of azides as a nitrogen source. In: Chemical Communications , 48 (44). pp. 5506-5508.

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Official URL: http://dx.doi.org/10.1039/C2CC31256E

Abstract

An efficient methodology to oxidize benzylic and cinnamyl alcohols to their corresponding nitriles in excellent yields has been developed. This methodology employs DDQ as an oxidant and TMSN3 as a source of nitrogen in the presence of a catalytic amount of Cu(ClO4)(2)center dot 6H(2)O.

Item Type: Journal Article
Additional Information: Copyrught for this article belongs Royal Society of Chemistry
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 16 Jun 2012 07:00
Last Modified: 16 Jun 2012 07:00
URI: http://eprints.iisc.ernet.in/id/eprint/44673

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