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Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine

Lamani, Manjunath and Guralamata, Ravikumara Siddappa and Prabhu, Kandikere Ramaiah (2012) Guanidine catalyzed aerobic reduction: a selective aerobic hydrogenation of olefins using aqueous hydrazine. In: CHEMICAL COMMUNICATIONS, 48 (52). pp. 6583-6585.

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Official URL: http://dx.doi.org/10.1039/c2cc32611f

Abstract

An efficient aerobic reduction of olefins, internal as well as terminal, is developed using guanidine as an organocatalyst. A remarkable chemoselectivity in reduction has been demonstrated in the presence of a variety of functional groups and protective groups and a selective reduction of a terminal olefin in the presence of an internal olefin is revealed.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to the Royal Society of Chemistry
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Jul 2012 12:52
Last Modified: 04 Jul 2012 12:52
URI: http://eprints.iisc.ernet.in/id/eprint/44775

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