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[Di-2-pyridyl ketone $N^{4},N^{4}$-(butane-1,4-diyl)thiosemicarbazonato-$k^{3}$ N,N',S]dioxovanadium(V)

Philip, Varughese and Manoj, E and Kurup, Prathapachandra MR and Nethaji, Munirathinam (2005) [Di-2-pyridyl ketone $N^{4},N^{4}$-(butane-1,4-diyl)thiosemicarbazonato-$k^{3}$ N,N',S]dioxovanadium(V). In: Acta Crystallographica Section C: Crystal Structure Communications, 61 (Part 1). M488-M490.

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Abstract

The $V^{V}$ atom in the title complex, $[V(C_{16}H_{16}N_{5}S)O_{2}]$, is five-coordinate in a highly distorted square-pyramidal geometry, with the pyridyl N, the azomethine N and the thiolate S atoms of the di-2-pyridyl ketone $N^{4},N^{4}$-(butane-1,4-diyl)thiosemicarbazone ligand and one oxo ligand occupying the basal coordination positions, while the second oxo ligand occupies the apical position. The molecules are interconnected by weak intermolecular interactions, mainly of the C-H...O type, involving the apical oxo atom.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Blackwell Publishing.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 16 Dec 2005
Last Modified: 19 Sep 2010 04:22
URI: http://eprints.iisc.ernet.in/id/eprint/4678

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