ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Growth and characterization of single crystal of pentachloropyridine

Rai, RN and Varma, KBR (2005) Growth and characterization of single crystal of pentachloropyridine. In: Journal of Crystal Growth, 285 (1&2). pp. 111-116.

[img] PDF
av89.pdf
Restricted to Registered users only

Download (215Kb) | Request a copy

Abstract

Bulk single crystals of pentachloropyridine (PCP) were grown by the Bridgman-Stockbarger method. The single crystalline nature of the grown crystals was confirmed using powder X-ray diffraction (XRD) techniques. These were transparent in the 315-2000nm range. The second harmonic generation (SHG) efficiency of polycrystalline materials using Kurtz powder technique was found to be twice that of the well-known organic nonlinear optical (NLO) material, urea. The mixing behavior of PCP with succinonitrile (SCN) and its effect on SHG and micro-hardness of PCP, along with the physicochemical properties of different compositions of PCP and SCN system were studied in detail. Bulk single crystals of the PCP solid solution containing 0.02 mole fraction of SCN have also been grown using the Bridgman-Stockbarger technique.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier.
Keywords: A1. Crystal growth; A1. Micro-hardness; A1. Optical properties; A1. Second harmonic generation; A1. Temperature profile; A2. Bridgman-Stockbarger
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 16 Dec 2005
Last Modified: 19 Sep 2010 04:22
URI: http://eprints.iisc.ernet.in/id/eprint/4686

Actions (login required)

View Item View Item