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A sequential RCM/fragmentation protocol towards chiral, stereodefined medium ring sesquiterpenoids. A carvone route to E- and Z-germacrenes

Mehta, Goverdhan and Kumaran, Senthil R (2005) A sequential RCM/fragmentation protocol towards chiral, stereodefined medium ring sesquiterpenoids. A carvone route to E- and Z-germacrenes. In: Tetrahedron Letters, 46 (51). pp. 8831-8835.

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Abstract

A short, flexible and enantioselective approach towards 10-membered germacratrienones, from the commercially available monoterpene chiron (-)-carvone, involving RCM and Grob-type fragmentation as the pivotal steps is delineated.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Dec 2005
Last Modified: 19 Sep 2010 04:22
URI: http://eprints.iisc.ernet.in/id/eprint/4789

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