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Correlations for binary phase equilibria in high-pressure carbon dioxide

Jha, Sujit Kumar and Madras, Giridhar (2005) Correlations for binary phase equilibria in high-pressure carbon dioxide. In: Fluid Phase Equilibria, 238 (2). pp. 174-179.

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Abstract

The high-pressure phase equilibrium in binary mixtures of carbon dioxide and various liquids such as benzene, toluene, m-xylene, chlorobenzene, 1,2-dichlorobenzene, low molecular weight alcohols, amides and a solid, hexachlorobenzene, was modeled using the Peng-Robinson equation of state with quadratic mixing rules. Though the technique of modeling is not new, the key conclusion of the study is that the two adjustable parameters, $k_{ij}$ and $l_{ij}$, vary linearly with the addition of functional groups. In addition, the adjustable parameters are found to be nearly independent of temperature and the same values of $k_{ij}$ and $l_{ij}$ can be used for a range of temperatures for the systems considered in the present study.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier.
Keywords: Phase equilibria; Supercritical fluids; Solubility; Model; Equation of state
Department/Centre: Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 10 Jan 2006
Last Modified: 19 Sep 2010 04:22
URI: http://eprints.iisc.ernet.in/id/eprint/5020

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