Mehta, Goverdhan and Umarye, Jayant D (2003) Studies towards the total synthesis of novel dolabellane-type diterpenoids: construction of the 5,11-fused bicyclic framework. In: Tetrahedron Letters, 44 (39). pp. 7285-7289.
An oxy-Cope protocol has been grafted on to a previously crafted hydroazulenic system to provide a facile entry into the 5,11-fused bicyclic skeleton present in the novel neodolabellane diterpenoids. Formation of a novel tricyclic diterpenoid framework, generated through a transannular cyclization in the 11-membered ring present in the neodolabellane skeleton and embodying a bridged cycloheptatriene moiety, has also been encountered.
|Item Type:||Journal Article|
|Additional Information:||Copyright for this article belongs to Elsevier Science Ltd.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry|
|Date Deposited:||06 Jul 2004|
|Last Modified:||19 Sep 2010 04:13|
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