Mehta, Goverdhan and Umarye, Jayant D (2003) Studies towards the total synthesis of novel dolabellane-type diterpenoids: construction of the 5,11-fused bicyclic framework. In: Tetrahedron Letters, 44 (39). pp. 7285-7289.
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Abstract
An oxy-Cope protocol has been grafted on to a previously crafted hydroazulenic system to provide a facile entry into the 5,11-fused bicyclic skeleton present in the novel neodolabellane diterpenoids. Formation of a novel tricyclic diterpenoid framework, generated through a transannular cyclization in the 11-membered ring present in the neodolabellane skeleton and embodying a bridged cycloheptatriene moiety, has also been encountered.
| Item Type: | Journal Article |
|---|---|
| Additional Information: | Copyright for this article belongs to Elsevier Science Ltd. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 06 Jul 2004 |
| Last Modified: | 19 Sep 2010 04:13 |
| URI: | http://eprints.iisc.ernet.in/id/eprint/503 |
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