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A deciduous directing group approach for the addition of aryl and vinyl nucleophiles to maleimides

Bettadapur, Kiran R and Lanke, Veeranjaneyulu and Prabhu, Kandikere Ramaiah (2017) A deciduous directing group approach for the addition of aryl and vinyl nucleophiles to maleimides. In: CHEMICAL COMMUNICATIONS, 53 (46). pp. 6251-6254.

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Official URL: http://dx.doi.org/10.1039/c7cc02392h

Abstract

A Rh( III)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally furnish a C-sp2-C-sp3 bond is presented. For the first time, derivatives of acrylic acid have been shown as surrogates for the unstable and expensive alkenyl boronic acids.

Item Type: Journal Article
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Additional Information: Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 28 Jun 2017 06:26
Last Modified: 28 Jun 2017 06:26
URI: http://eprints.iisc.ernet.in/id/eprint/57267

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