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Total Synthesis of Sch 725674

Vaithegi, Kannan and Prasad, Kavirayani R (2018) Total Synthesis of Sch 725674. In: TETRAHEDRON, 74 (20). pp. 2488-2492.

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Official URL: https://dx.doi.org/10.1016/j.tet.2018.04.014

Abstract

A concise total synthesis of the macrolactone natural product Sch 725674 is accomplished starting from commercially available 2-deoxy-o-ribose. Pivotal reactions employed in the synthesis include the addition of 4-pentenylmagnesium bromide to the lactol derived from 2-deoxy-o-ribose, olefin cross metathesis and Yamaguchi macrolactonization. (C) 2018 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
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Additional Information: Copy right of this article belong toPERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 13 Jun 2018 15:26
Last Modified: 13 Jun 2018 15:26
URI: http://eprints.iisc.ernet.in/id/eprint/60006

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