Kumar, P and Chakraborty, S and Srinivasan, K and Dutta, P (2003) Studies on Transport Phenomena during Directional Solidification of a Noneutectic Binary Solution Cooled from the Top. In: Metallurgical and Materials Transactions B, 34 (6). pp. 899-909.
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In this article, we investigate the effects of laminar natural convection on directional solidification of binary fluids with noneutectic compositions when cooled and solidified from the top. The study is performed using aqueous ammonium chloride solution as the model fluid. In the first case, the initial concentration of ammonium chloride is less than the eutectic composition, leading to an aiding of the double-diffusive convection. In this case, solidification leads to the formation of a diffused matrix of dendritic crystals (mushy region) separating the pure solid and liquid regions. The mushy interface is characterized by a waviness, which is caused by a Rayleigh–Benard type of cellular motion in the liquid region. The cellular motions, which are caused by thermal and solutal buoyancy, cease once the thickness of the liquid layer falls below a critical value. The second case leads to a unique situation, in which crystals nucleated at the top wall of the cavity detach and descend through the lighter bulk fluid and, finally, settle at the floor of the cavity. In both the aforementioned cases, the features of convective transport are visualized using a sheet of laser light scattered through neutrally buoyant glass particles seeded in the solution. Numerical simulations are also performed for the first case, and the agreement with experimental results is found to be good.
|Item Type:||Journal Article|
|Additional Information:||The Copyright belongs to Minerals, Metals & Materials Society and ASM International.|
|Department/Centre:||Division of Mechanical Sciences > Mechanical Engineering|
|Date Deposited:||12 Apr 2006|
|Last Modified:||08 Jul 2011 09:52|
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