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Organically-templated metal sulfates, selenites and selenates

Rao, CNR and Behera, JN and Dan, Meenakshi (2006) Organically-templated metal sulfates, selenites and selenates. In: Chemical Society Reviews, 35 (4). pp. 375-387.

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Abstract

The literature on inorganic open-framework materials abounds in the synthesis and characterization of metal silicates, phosphates and carboxylates. Most of these materials have an organic amine as the template. In the last few years, it has been shown that anions such as sulfate, selenite and selenate can also be employed to obtain organically templated open-framework materials. This tutorial review provides an up-to-date survey of organically templated metal sulfates, selenites and selenates, prepared under hydrothermal conditions. The discussion includes one-, two-, and three-dimensional structures of these materials, many of which possess open architectures. The article should be useful to practitioners of inorganic and materials chemistry, besides students and teachers. The article serves to demonstrate how most oxy-anions can be used to build complex structures with metal–oxygen polyhedra.

Item Type: Journal Article
Additional Information: The Copyright belongs to Royal Society of Chemistry.
Keywords: Open-framework structures;Dimensional Zinc Phosphates;Unusual Magnetic-Properties;Crystal-structure;Uranium sulfates;Hydrothermal synthesis;Layered structures;Kagome lattice;Temperature crystallization;Gallium fluorophosphate
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 18 Apr 2006
Last Modified: 27 Aug 2008 11:53
URI: http://eprints.iisc.ernet.in/id/eprint/6329

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