ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing $P(OH)_2(OMe)$ ligand

Nagaraja, CM and Nethaji, Munirathinam and Jagirdar, Balaji R (2004) Novel double dealkylation of trialkylphosphite in the presence of an acid: synthesis and characterization of a 16-electron ruthenium complex bearing $P(OH)_2(OMe)$ ligand. In: Inorganic Chemistry Communications, 7 (5). pp. 654-656.

[img] PDF
Novel_double-418-pdf.pdf
Restricted to Registered users only

Download (191Kb) | Request a copy

Abstract

A stable, coordinatively unsaturated, 16-electron ruthenium complex bearing $P(OH)_2(OMe)$ has been synthesized and characterized. It reacts with $H_2$ resulting in a highly acidic dihydrogen complex.

Item Type: Journal Article
Additional Information: The copyright belongs to Elsevier.
Keywords: Acidity;Dihydrogen complex;Hydride complex;Diphosphine;Phosphite;Ruthenium
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 10 May 2006
Last Modified: 19 Sep 2010 04:26
URI: http://eprints.iisc.ernet.in/id/eprint/6661

Actions (login required)

View Item View Item