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Catalytic epoxidation of cyclic vinylsilanes by ruthenium(II) complexes under aerobic conditions

Srikanth, Abirami and Nagendrappa, Gopalpur and Chandrasekaran, Srinivasan (2003) Catalytic epoxidation of cyclic vinylsilanes by ruthenium(II) complexes under aerobic conditions. In: Tetrahedron, 59 (39). pp. 7761-7765.

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Abstract

A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ruthenium(II) bisoxazoline complex 2 with molecular oxygen. An attempt has been made to understand the role of โ€“$SiMe_3$ group on the rate of epoxidation process.

Item Type: Journal Article
Additional Information: The Copyright belongs to Elsevier.
Keywords: Epoxidation;Ruthenium;Vinylsilanes;Molecular oxygen
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 19 May 2006
Last Modified: 19 Sep 2010 04:26
URI: http://eprints.iisc.ernet.in/id/eprint/6740

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