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Facile conversion of amides and lactams to selenoamides and selenolactams using tetraethylammonium tetraselenotungstate

Saravanan, Vadivelu and Mukherjee, Chandan and Das, Saibal and Chandrasekaran, Srinivasan (2004) Facile conversion of amides and lactams to selenoamides and selenolactams using tetraethylammonium tetraselenotungstate. In: Tetrahedron Letters, 45 (4). pp. 681-683.

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Abstract

Chloroiminium salts generated in situ from amides and lactams using $(COCl)_2$ or $POCl_3$ react very readily with the new selenium transfer reagent, tetraethylammonium tetraselenotungstate, $(Et_4N)_2WSe_4,$ 1, to afford the corresponding selenoamides and selenolactams in excellent yields under mild reaction conditions.

Item Type: Journal Article
Additional Information: The copyright belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 01 Jun 2006
Last Modified: 19 Sep 2010 04:28
URI: http://eprints.iisc.ernet.in/id/eprint/7246

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