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Dissociation dynamics of fluorinated alkyl iodides at 222 and 236 nm

Kavita, K and Das, Puspendu K (2001) Dissociation dynamics of fluorinated alkyl iodides at 222 and 236 nm. In: Chemical Physics Letters, 338 (2-3). pp. 118-122.

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Abstract

$I^*(^2P_{1/2})$ quantum yield has been measured for a series of fluorinated alkyl iodides at two different wavelengths in the blue wing of their A-band. The yields are much higher for the fluorinated iodides than their corresponding alkyl iodide analogs at 222 as well as 236 nm. The $I^*$ quantum yield at 222 nm is, in general, larger than that at 236 nm which is opposite to what has been found in normal alkyl iodide dissociation in the A-band. This difference in fluorinated iodides has been explained by invoking the participation of the B-band states in the dissociation dynamics.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 14 Jun 2006
Last Modified: 19 Sep 2010 04:29
URI: http://eprints.iisc.ernet.in/id/eprint/7620

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