Muthu, Victor DS and Chandrabhas, N and Sood, AK and Venkatesan, K and Venugopalan, P and Jayaraman, A (1992) High-Pressure Raman Study of K and T Forms of the Octachloro Cyclic Phosphazene Tetramer $P_4N_4Cl_8$. In: Journal of Raman Spectroscopy, 23 (11). 611 -614.
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The octachloro cyclic phosphazene tetramer $P_4N_4Cl_8$ was studied by high-pressure Raman spectroscopy up to 10 GPa in the K form (boat-shaped molecule) and in the T form (chair-shaped molecule). There are pressure-induced phase transitions in the crystal with the K-form molecules. There is a conformation change from the T to the K form under a non-hydrostatic pressure of less than 0.7 GPa.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to John Wiley & Sons, Inc.|
|Department/Centre:||Division of Chemical Sciences > Organic Chemistry
Division of Physical & Mathematical Sciences > Physics
|Date Deposited:||23 Jan 2007|
|Last Modified:||19 Sep 2010 04:31|
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