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Synthetic Utility of Copper(I) Phenoxfde Complexes

Narasimhamurthy, N and Samuelson, AG (1989) Synthetic Utility of Copper(I) Phenoxfde Complexes. In: Proceedings of the Indian National Science Academy, Part A: Physical Sciences, 55 A (2). pp. 383-391.

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Abstract

Several sulphur containing organic molecules react with copper(I) phenoxides under extremely mild conditions to give cuprous sulphide and an organic phenoxide. The reaction proceeds through nucleophilic substitution on the coordinated sulphur compound. The nature of the product obtained is governed by the ancillary ligands around copper(I). The high yields of the organic product obtained make these reactions extremely attractive as methods of synthesis for these compounds.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Indian National Science Academy.
Keywords: Copper(I);Phenoxide Complexes;Thiophilic Reactions
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 18 Aug 2006
Last Modified: 19 Sep 2010 04:31
URI: http://eprints.iisc.ernet.in/id/eprint/8292

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