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Synthesis of large generation poly(propyl ether imine) (PETIM) dendrimers

Jayamurugan, Govindasamy and Jayaraman, Narayanaswamy (2006) Synthesis of large generation poly(propyl ether imine) (PETIM) dendrimers. In: Tetrahedron, 62 (41). pp. 9582-9588.

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Abstract

Large generation poly(propyl ether imine) (PETIM) dendrimers are synthesized in iterative synthetic cycles of two reductions and two Michael addition reactions. Dendrimers up to sixth generation, containing up to 128 peripheral functionalities, are synthesized. Growth of the PETIM dendrimers, possessing a tertiary amine as the branch juncture and an ether as the linker component, is assessed systematically by routine spectroscopic methods. The peripheries of these dendrimers possess either alcohols, amines, carboxylic acids, esters, or nitriles, thereby opening up possibilities for varied studies involving PETIM dendrimers.

Item Type: Journal Article
Additional Information: Copyright of this article belongs to Elsevier.
Keywords: Dendrimers;Iterative synthesis;Michael addition;Raney cobalt
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Nov 2006
Last Modified: 19 Sep 2010 04:32
URI: http://eprints.iisc.ernet.in/id/eprint/8884

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