Biswas, Ranjit and Bagchi, Biman (1998) Ion solvation dynamics in supercritical water. In: Chemical Physics Letters, 290 (1-3). pp. 223-228.
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A theoretical study of ionic solvation dynamics in supercritical water is presented. The short-time decay of the calculated equilibrium solvation energy time correlation function $(S_E(t))$ is found to be in good agreement with the recent computer E simulation results. The simulated long-time decay is, however, somewhat slower than that which is predicted by the present theory. Two plausible molecular explanations for the slow long-time decay of $(S_E(t))$ are offered.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier.|
|Department/Centre:||Division of Chemical Sciences > Solid State & Structural Chemistry Unit|
|Date Deposited:||03 Jan 2007|
|Last Modified:||19 Sep 2010 04:33|
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