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Thiabowls: synthesis, molecular structure and the solid state architecture of tetrathia-[4]-peristylane

Mehta, Goverdhan and Gagliardini, Vanessa and Schaefer, Carsten and Gleiter, Rolf (2003) Thiabowls: synthesis, molecular structure and the solid state architecture of tetrathia-[4]-peristylane. In: Tetrahedron Letters, 44 (52). pp. 9313-9316.

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Abstract

Synthesis of tetrathia-[4]-peristylane, the first thiabowl, from the dimer of cyclooctatetraene has been accomplished. The X-ray crystal structure of the tetrathiabowl indicates significant departure from the expected C4v symmetry and in the solid state it exhibits a multi-columnar arrangement and a novel ‘self-inclusion’ phenomenon, directed by a network of S···S and CH···S interactions.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier Science.
Keywords: cyclic thioethers;intermolecular interactions;oxygen–sulfur exchange
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 08 Jul 2004
Last Modified: 19 Sep 2010 04:13
URI: http://eprints.iisc.ernet.in/id/eprint/996

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